聚碳酸酯(PC)是碳酸的聚酯类,碳酸本身并不稳定,但其衍生物(如光气,尿素,碳酸盐,碳酸酯)都有一定稳定性.
按醇结构的不同,可将聚碳酸酯分成脂族和芳族两类.
脂族聚碳酸酯.如聚亚乙基碳酸酯,聚三亚甲基碳酸酯及其共聚物,熔点和玻璃化温度低,强度差,不能用作结构材料;但利用其生物相容性和生物可降解的特性,可在药物缓释放载体,手术缝合线,骨骼支撑材料等方面获得应用.
聚碳酸酯耐弱酸,耐弱碱,耐中性油.
聚碳酸酯不耐紫外光,不耐强碱.
PC是一种线型碳酸聚酯,分子中碳酸基团与另一些基团交替排列,这些基团可以是芳香族,可以是脂肪族,也可两者皆有.双酚A型PC是最重要的工业产品.
PC是几乎无色的玻璃态的无定形聚合物,有很好的光学性.PC高分子量树脂有很高的韧性,悬臂梁缺口冲击强度为600~900J/m,未填充牌号的热变形温度大约为130°C ,玻璃纤维增强后可使这个数值增加10°的弯曲模量可达2400MPa以上,树脂可加工制成大的刚性制品.低于100°C 时,在负载下的蠕变率很低.PC耐水解性差,不能用于重复经受高压蒸汽的制品.
PC主要性能缺陷是耐水解稳定性不够高,对缺口敏感,耐有机化学品性,耐刮痕性较差,长期暴露于紫外线中会发黄.和-树脂一样,PC容易受某些有机溶剂的侵蚀.
PC材料具有阻燃性,耐磨.抗氧化性.
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